钙钛矿高转换效率光伏材料合成技术进展综述

Progress in Synthesis and Application of Perovskite Photovoltaic Materials

程方

CHENG Fang

山东省电力行业协会，山东济南250100

摘要(Abstract)：

光伏发电系统具有显著的能源、环保与经济效益，能显著降低碳排放，未来将成为世界能源供应的主体。随着社会对能源绿色化意识的逐渐提高和化工合成技术的进步，高光电转换效率太阳能电池的研究和开发已成为当下研究热点。其中，钙钛矿（ABX3）材料由于其光电转换效率高、成本低以及光学可调性强等优点而成为新一代太阳能电池最有前途的材料之一。重点介绍钙钛矿太阳能电池发电原理与发展现状，并从不同化学成分角度分析比较了不同类型太阳能电池的技术优势和发展前景，包括有机-无机杂化钙钛矿太阳能电池、无机钙钛矿太阳能电池、纳米尺度无机钙钛矿材料及其他类型太阳能电池材料，为下一步钙钛矿高转换效率光伏材料合成技术发展路线提供了参考。Photovoltaic power generation has significant energy，environmental and economic benefits，and can significantly reduce carbon emissions.It will become the main source of global energy supply in the future.With the gradual improvement of society's awareness of energy greening and the advancement of chemical synthesis technology，the research and development of high photoelectric conversion efficiency solar cells has become a current research hotspot. Among them，perovskite（ABX3） materials have become one of the most promising materials for new-generation solar cells due to their high photoelectric conversion efficiency，low cost，and strong optical tunability.The principle and development status of perovskite solar cells was introduced.Then，the technical advantages and development prospects of different types of solar cells from the perspective of different chemical compositions were analyzed and compared，including organic-inorganic hybrid perovskite solar cells，inorganic perovskite solar cells，nanoscale inorganic perovskite materials and other types of solar cell materials，which provide a reference for the next step in the development of perovskite high conversion efficiency photovoltaic materials synthesis technology.

关键词(KeyWords)：钙钛矿太阳能电池；光伏；光电转换效率
perovskite solar cells；photovoltaic；photoelectric conversion efficiency

基金项目(Foundation):

作者(Author): 程方

CHENG Fang

DOI: 10.20097/j.cnki.issn1007-9904.2023.10.003

收稿日期(Received): 2023-06-05; 修回日期(Revised): 2023-08-18

参考文献(References)：

[1 ]GRÄTZEL M.Photoelectrochemical cells[J].Nature,2001,414(6861):338-344.

[2]国家统计局.中华人民共和国2022年国民经济和社会发展统计公报[EB/OL].(2023-02-28)[2023-04-18].http：//www.gov.cn/xinwen/2023-2/28/content_5743623.htm.

[3]陈舒涵，刘晓春，王丽娜，等.钙钛矿材料在热载流子太阳能电池中的研究进展[J].激光与光电子学进展，2023,60(13):264-275.

CHEN Shuhan,LIU Xiaochun,WANG Lina,et al.Research progress of perovskite materials in hot carrier solar cells[J].Laser&Optoelectronics Progress,2023,60(13):264-275.

[4]李亮.世界纪录效率的全钙钛矿叠层太阳电池：3D/3D异质结助力效率提升[J].科学通报，2023,68(22):2 860-2 861.

LI Liang.World record of all-perovskite tendem solar cells:3D/3Dheterojunctions boost efficiency improvement[J].Chinese Science Bulletin,2023,68(22):2 860-2 861.

[5]CHAPIN D M,FULLER C S,PEARSON G I.A new silicon P-Njunction photocell for converting solar radiation into electrical power[J].Journal of Applied Physics,1954,25(5):676.

[6]KABIR M,SHAHAHMAD S A,LIM V,et al.Amorphous silicon single-junction thin-film solar cell exceeding 10%efficiency by design optimization[J].International Journal of Photoenergy,2012,2012:1 415-1 424.

[7]HAN G,ZHANG S,BOIX P P,et al.Towards high efficiency thin film solar cells[J].Progress in Materials Science,2017,87:246-291.

[8]曹希文，张雅希，杨小国，等.无机薄膜太阳能电池光伏材料的研究进展[J].中国陶瓷工业，2023,30(1):48-56.

CAO Xiwen,ZHANG Yaxi,YANG Xiaoguo,et al.Research progress of photovoltaic materials for inorganic thin film solar cells[J].China Ceramic Industry,2023,30(1):48-56.

[9]HE F,LI J,LIN S,et al.Semitransparent CdTe solar cells with CdCl2treated absorber towards the enhanced photovoltaic conversion efficiency[J].Solar Energy,2021,214:196-204.

[10]SABRINA R,SHEIKH R.Photovoltaic performance enhancement in CdTe thin-film heterojunction solar cell with Sb2S3as hole transport layer[J].Solar Energy,2021,230:605-617.

[11]关丽，李明军，李旭，等.有机金属卤化物钙钛矿太阳能电池的研究进展[J].科学通报，2015,60(7):581-592.

GUAN Li,LI Mingjun,LI Xu,et al.Recent progress of organohalide perovskite solar cells[J].Chinese Science Bulletin,2015,60(7):581-592.

[12]於黄忠，彭俊彪.共混型聚合物太阳电池原理及研究进展[J].化学进展，2007(11):1 689-1 694.

YU Huangzhong,PENG Junbiao.Principle and progress of polymer solar cells[J].Progress in Chemistry,2007(11):1 689-1 694.

[13]SHARMA R,LEE H,BORSE K,et al.Ga-doped ZnO as an electron transport layer for PffBT4T-2OD:PC70BM organic solar cells[J].Organic Electronics,2017,43:207-213.

[14]GUI Z,LIU X,MING S,et al.Efficient organic solar cells employing ytterbium ion-doped zinc oxide as cathode transporting layer[J].Organic Electronics,2018,53:296-302.

[15]SNAITH H J.Perovskites:the emergence of a new era for low-cost,high-efficiency solar cells[J].Journal of Physical Chemistry Letters,2013,4(21):3 623-3 630.

[16]LI C,LU X,DING W,et al.Formability of ABX3(X=F,Cl,Br,I)halide perovskites[J].Acta Crystallographica,2008,B64:702-707.

[17]HO-BAILLIE A,ZHANG M,LAU C F J,et al.Untapped potentials of inorganic metal halide perovskite solar cells[J].Joule,2019,3(4):938-955.

[18]AHMAD M,REHMAN G,ALI L,et al.Structural,electronic and optical properties of CsPbX3(X=Cl,Br,I)for energy storage and hybrid solar cell applications[J].Journal of Alloys and Compounds,2017,705:828-839.

[19]GREEN M A,HO-BAILLIE A,SNAITH H J.The emergence of perovskite solar cells[J].Nature Photonics,2014,8:506-514.

[20]WEBER M,GUENTHER R,CLAUS W.Economy and society:an outline of interpretive sociology[M].Berkeley:University of California Press,1978.

[21]MIYASAKA T,SHIRAI Y,TESHIMA K,et al.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].Journal of the American Chemical Society,2009,131(17):6 050-6 051.

[22]YOO J,SEO G,CHUA M R,et al.Efficient perovskite solar cells via improved carrier management[J].Nature,2021,590:587-594.

[23]IM J,LEE C,LEE J,et al.6.5%efficient perovskite quantum-dotsensitized solar cell[J].Nanoscale,2011,3(10):4 088-4 093.

[24]JENG J,CHIANG Y,LEE M,et al.CH3NH3PbI3perovskite/fullerene planar-heterojunction hybrid solar cells[J].Advanced Materials,2013,25(27):3 727-3 732.

[25]LUO D,YANG W,WANG Z,et al.Enhanced photovoltage for inverted planar heterojunction perovskite solar cells[J].Science,2018,360(6396):1 442-1 446.

[26]KIM H,LEE C R,IM J H,et al.Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Scientific Reports,2012,2:591.

[27]KANATZIDIS M,CHANG R P H,HE J,et al.All-solid-state dyesensitized solar cells with high efficiency[J].Nature,2012,485:486-489.

[28]LEE M M,TEUSCHER J,MIYASAKA T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643-647.

[29]BURSCHKA J,PELLET N,MOON S,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499:316-319.

[30]LIU M,JOHNSTON M,SNAITH H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501:395-398.

[31]ZHOU H,CHEN Q,LI G,et al.Interface engineering of highly efficient perovskite solar cells[J].Science,2014,345(6196):542-546.

[32]LI M,WANG Z,ZHUO M,et al.Pb-Sn-Cu ternary organometallic halide perovskite solar cells[J].Advanced Materials,2018,30(20):1800258.

[33]JEONG J,KIM M,SEO J,et al.Pseudo-halide anion engineering forα-FAPbI3perovskite solar cells[J].Nature,2021,592:381-385.

[34]PANG S,HU H,ZHANG J,et al.NH2CH=NH2PbI3:an alternative organolead iodide perovskite sensitizer for mesoscopic solar cells[J].Chemistry of Materials,2014,26(3):1 485-1 491.

[35]JEON N,NOH J,YANG W S,et al.Compositional engineering of perovskite materials for high-performance solar cells[J].Nature,2015,517:476-480.

[36]MIN H,KIM M,LEE S,et al.Efficient,stable solar cells by using inherent bandgap of a-phase formamidinium lead iodide[J].Science,2019,366(6466):749-753.

[37]SALIBA M,MATSUI T,SEO J Y,et al.Cesium-containing triple cation perovskite solar cells:improved stability,reproducibility and high efficiency[J].Energy and Environmental Science,2016,9:1 989-1 997.

[38]MARIOTTI S,JAGER K,DIEDERICH M,et al.Monolithic perovskite/silicon tandem solar cells fabricated using industrial ptype polycrystalline silicon on oxide/passivated emitter and rear cell silicon bottom cell technology[J].Solar RRL,2022,6(4):2101066.

[39]CHIN X,TURKAY D,STEELE J,et al.Interface passivation for31.25%-efficient perovskite/silicon tandem solar cells[J].Science,2023,381(6653):59-63.

[40]马晓辉，杨立群，郑士建，等.全无机钙钛矿太阳电池：现状与未来[J].化学进展，2020,32(10):1 608-1 632.

MA Xiaohui,YANG Liqun,ZHENG Shijian,et al.All-inorganic perovskite solar cells:status and future[J].Progress in Chemistry,2020,32(10):1 608-1 632.

[41]楚树勇，田菊梅，张正国.无机钙钛矿材料的低温制备及光伏应用进展[J].石油化工应用，2022,41(9):1-6.

CHU Shuyong,TIAN Jumei,ZHANG Zhengguo.Progress in low temperature synthesis and application of inorganic perovskite materials[J].Petrochemical Industry Application,2022,41(9):1-6.

[42]张世宁，张贤，杨爽，等.钙钛矿太阳能电池的内建电场调控策略研究进展[J].科学通报，2023,68(1):39-52.

ZHANG Shining,ZHANG Xian,YANG Shuang,et al.Progress on strategies to control the built-in electric field of perovskite solar cells[J].Chinese Science Bulletin,2023,68(1):39-52.

[43]张生鹏，刘月秋，李云凤，等.钙钛矿太阳能电池研究进展与发展现状[J].光源与照明，2022(12):23-25.

ZHANG Shengpeng,LIU Yueqiu,LI Yunfeng,et al.Research progress and development status of perovskite solar cells[J].Lamps&Lighting,2022(12):23-25.

[44]张恒宾，赵建红，柳清菊，等.CsPbI2Br无机钙钛矿太阳能电池的研究进展[J].功能材料与器件学报，2022,28(5):426-432.

ZHANG Hengbin,ZHAO Jianhong,LIU Qingju,et al.Research progress of CsPbI2Br inorganic perovskite solar cells[J].Journal of Functional Materials and Devices,2022,28(5):426-432.

[45]YU B,SHI J,TAN S,et al.Efficient(>20%)and stable allInorganic cesium lead triiodide solar cell enabled by thiocyanate molten salts[J].Angewandte Chemie International Edition,2021,60(24):13 436-13 443.

[46]HAN Y,ZHAO H,DUAN C,et al.Controlled n-doping in airstable CsPbI2Br perovskite solar cells with a record efficiency of16.79%[J].Advanced Functional Materials,2020,30(12):1909972.

[47]KIM K S,JIN I S,PARK S H,et al.Methylammonium iodidemediated controlled crystal growth of CsPbI2Br films for efficient and stable all-inorganic perovskite solar cells[J].ACS Applied Materials&Interfaces,2020,12(32):36 228-36 236.

[48]NAM J K,JUNG M S,CHAI S U,et al.Unveiling the crystal formation of cesium lead mixed-halide perovskites for efficient and stable solar cells[J].The Journal of Physical Chemistry Letters,2017,8(13):2 936-2 940.

[49]欧阳颖，秦永宁，马智.纳米钙钛矿的性能及应用进展[J].天津化工，2002(1):4-5.

OUYANG Ying,QIN Yongning,MA Zhi.Properties and application progress of nano-perovskite[J].Tianjin Chemical Industry,2002(1):4-5.

[50]杨洁，皮明雨，张丁可，等.低维钙钛矿光电探测器研究进展[J].发光学报，2021,42(6):755-773.

YANG Jie,PI Yuming,ZHANG Dingke,et al.Recent progress on low-dimensional perovskite photodetectors[J].Chinese Journal of Luminescence,2021,42(6):755-773.

[51]MOREELS I,LAMBERT K,SMEETS D,et al.Size-dependent optical properties of colloidal PbS quantum dots[J].ACS Nano,2009,3(10):3 023-3 030.

[52]石文奇，田宏，陆玉新，等.金属卤化物钙钛矿纳米光电材料的研究进展[J].物理学报，2021,70(8):153-170.

SHI Wenqi,TIAN Hong,LU Yuxin,et al.Research progress of metal halide perovskite nanometer optoelectronic materials[J].Acta Physica Sinica,2021,70(8):153-170.

[53]DOU L,WONG A B,YU Y,et al.Atomically thin two-dimensional organic-inorganic hybrid perovskites[J].Science,2015,349(6255):1 518-1 521.

[54]PROTESESCU L,YAKUNIN S,BODNARCHUK M I,et al.Nanocrystals of cesium lead halide perovskites(CsPbX3,X=Cl,Br,and I):novel optoelectronic materials showing bright emission with wide color gamut[J].Nano letters,2015,15(6):3 692-3 696.

[55]ZHANG D,EATON S W,YU Y,et al.Solution-phase synthesis of cesium lead halide perovskite nanowires[J].Journal of the American Chemical Society,2015,137(29):9 230-9 233.

[56]PENG J,WALTER D,REN Y,et al.Nanoscale localized contacts for high fill factors in polymer-passivated perovskite solar cells[J].Science,2021,371(6527):390-395.

[57]张美荣，祝曾伟，杨晓琴，等.迈向效率大于30%的钙钛矿/晶硅叠层太阳能电池技术的研究进展[J].物理学报，2023,72(5):156-170.

ZHANG Meirong,ZHU Cengwei,YANG Xiaoqin,et al.Research progress of perovskite/crystalline silicon tandem solar cells with efficiency of over 30%[J].Acta Physica Sinica,2023,72(5):156-170.

[58]JOHNSTON M B,HERZ L M.Hybrid perovskites for photovoltaics:charge-carrier recombination,diffusion,and radiative efficiencies[J].Accounts of Chemical Research,2016,49(1):146-154.

[59]BRITT J,FEREKIDES C.Thin-film Cds/CdTe solar cell with15.8%efficiency[J].Applied Physics Letters,1993,62:2 851-2 852.

[60]ZHAI Y T,CHEN S Y,YANG J H,et al.Structural diversity and electronic properties of Cu2SnX3(X=S,Se):a first-principles investigation[J].Physical Review B,2011,84:075213.

[61]NEHA K,SANJAY K,KUMAR S.A comparative study of different materials used for solar photovoltaics technology[J].Materials Today:Proceedings,2022,66(8):3 522-3 528.

[62]密保秀，高志强，邓先宇，等.基于有机薄膜的太阳能电池材料与器件研究进展[J].中国科学（B辑：化学），2008(11):957-975.

MI Baoxiu,GAO Zhiqiang,DENG Xianyu,et al.Research progress of solar cell materials and devices based on organic thin films[J].Scientia Sinica(Chimica),2008(11):957-975.

[63]WOHRLE D,MEISSNER D.Organic solar cells[J].Advanced Materials,1991,3(3):129-138.

[64]TANG C W,ALBRECHT A C.Photovoltaic effects of metalchlorophyll-a-metal sandwich cells[J].The Journal of Chemical Physics,1975,62:2 139-2 149.

[65]ZHAO G,HE Y,LI Y F.6.5%efficiency of polymer solar cells based on poly(3-hexylthiophene)and indene-C60bisadduct by device optimization[J].Advanced Materials,2010,22(39):4 355-4 358.